(12·Ö)

ij³§·ÏË®Öк¬5.00¡Á10-3mol?L-1µÄ£¬Æ䶾ÐԽϴó¡£Ä³Ñо¿ÐÔѧϰС×éΪÁ˱ä·ÏΪ±¦£¬½«·ÏË®´¦ÀíµÃµ½´ÅÐÔ²ÄÁÏ£¨µÄ»¯ºÏ¼ÛÒÀ´ÎΪ+3¡¢+2£©£¬Éè¼ÆÁËÈçÏÂʵÑéÁ÷³Ì£º

 


£¨1£©µÚ¢Ù²½·´Ó¦µÄÀë×Ó·½³ÌʽÊÇ                                                 

£¨2£©µÚ¢Ú²½ÖÐÓÃPHÊÔÖ½²â¶¨ÈÜÒºPHµÄ²Ù×÷ÊÇ£º

                                                                               

£¨3£©µÚ¢Ú²½¹ýÂ˵õ½µÄÂËÔüÖÐÖ÷Òª³É·Ö³ýCr£¨OH£©3Í⣬»¹ÓР                     

£¨4£©Óûʹ1L¸Ã·ÏË®ÖеÄÍêȫת»¯Îª¡£ÀíÂÛÉÏÐèÒª¼Ó

Èë         gFeSO4?7H2O¡£

¢Å Cr2O72- + 6Fe2++14H+ = 2Cr3+ + 6Fe3+ + 7H2O

¢Æ½«Ò»Ð¡¿éPHÊÔÖ½·ÅÔÚ±íÃæÃóÉÏ£¬Óò£Á§°ôպȡÉÙÁ¿´ý²âÒº£¬µãÔÚPHÊÔÖ½ÉÏ£¬Óë±ê×¼±ÈÉ«¿¨¶ÔÕÕ

¢Ç Fe(OH)3  \Fe(OH)2

¢È  13.9

Á·Ï°²áϵÁдð°¸
Ïà¹ØÏ°Ìâ

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£º

(12·Ö)

ij³§·ÏË®Öк¬5.00¡Á10-3mol?L-1µÄ£¬Æ䶾ÐԽϴó¡£Ä³Ñо¿ÐÔѧϰС×éΪÁ˱ä·ÏΪ±¦£¬½«·ÏË®´¦ÀíµÃµ½´ÅÐÔ²ÄÁÏ£¨µÄ»¯ºÏ¼ÛÒÀ´ÎΪ+3¡¢+2£©£¬Éè¼ÆÁËÈçÏÂʵÑéÁ÷³Ì£º

£¨1£©µÚ¢Ù²½·´Ó¦µÄÀë×Ó·½³ÌʽÊÇ                                                 

£¨2£©µÚ¢Ú²½ÖÐÓÃPHÊÔÖ½²â¶¨ÈÜÒºPHµÄ²Ù×÷ÊÇ£º

                                                                              

£¨3£©µÚ¢Ú²½¹ýÂ˵õ½µÄÂËÔüÖÐÖ÷Òª³É·Ö³ýCr£¨OH£©3Í⣬»¹ÓР                     

£¨4£©Óûʹ1L¸Ã·ÏË®ÖеÄÍêȫת»¯Îª¡£ÀíÂÛÉÏÐèÒª¼ÓÈë           GFeSO4?7H2O¡£

²é¿´´ð°¸ºÍ½âÎö>>

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£ºÔĶÁÀí½â

(10·Ö)

Ëæ׏¤ÒµµÄѸËÙ·¢Õ¹£¬²úÉúµÄ·ÏË®¶ÔË®ÌåµÄÎÛȾҲÈÕÇ÷ÑÏÖØ¡£Í¨¹ý¿ØÖÆÈÜÒºµÄpH¶Ô¹¤Òµ·ÏË®ÖеĽðÊôÀë×Ó½øÐзÖÀëÊÇʵ¼Ê¹¤×÷Öо­³£Ê¹Óõķ½·¨¡£Ï±íÊdz£ÎÂϽðÊôÇâÑõ»¯ÎïµÄKsp(³ÁµíÈܽâƽºâ³£Êý)ºÍ½ðÊôÀë×ÓÔÚijŨ¶ÈÏ¿ªÊ¼³ÁµíËùÐèµÄpH(±íÖÐŨ¶ÈΪÏàÓ¦pHʱÈÜÒºÖÐÓйؽðÊôÀë×Ó²úÉú³ÁµíµÄ×îСŨ¶È£»µ±ÈÜÒºÖнðÊôÀë×ÓŨ¶ÈСÓÚ10-5 mol¡¤L-1ʱͨ³£ÈÏΪ¸ÃÀë×Ó³ÁµíÍêÈ«)¡£

½ðÊôÀë×Ó

Ksp

pH(10-1 mol¡¤L-1)

pH(10-5 mol¡¤L-1)

Fe3+

4.0¡Á10-38

2.7

3.7

Cr3+

6.0¡Á10-31

4.3

5.6

Cu2+

2.2¡Á10-20

4.7

6.7

Ca2+

4.0¡Á10-5

12.3

14.3

(1)ij³§ÅųöµÄ·ÏË®Öк¬ÓÐCu2+ºÍFe3+£¬²âµÃÆäŨ¶È¾ùСÓÚ0.1 mol¡¤L-1¡£Îª³ýÈ¥ÆäÖеÄFe3+£¬»ØÊÕÍ­£¬Ðè¿ØÖƵÄpH·¶Î§ÊÇ_______________________________¡£

(2)ΪÁË´¦Àíº¬ÓÐCr2O72-ËáÐÔÈÜÒºµÄ¹¤Òµ·ÏË®£¬²ÉÓÃÈçÏ·½·¨£ºÏò·ÏË®ÖмÓÈËÊÊÁ¿NaCl£¬ÒÔFeΪµç¼«½øÐеç½â£¬¾­¹ýÒ»¶Îʱ¼ä£¬ÓÐCr(OH)3ºÍFe(OH)3³ÁµíÉú³ÉÅųö£¬´Ó¶øʹ·ÏË®Öиõº¬Á¿µÍÓÚÅŷűê×¼¡£

 ¢ÙCr2O72-ת±äΪCr3+µÄÀë×Ó·½³ÌʽΪ______________________¡£

 ¢ÚpH¶Ô·ÏË®ÖÐCr2O72-È¥³ýÂʵÄÓ°ÏìÈçÓÒͼ¡£ÄãÈÏΪµç½â¹ý³ÌÖÐÈÜÒºµÄpHÈ¡ÖµÔÚ______·¶Î§ÄÚ¶Ô½µµÍ·ÏË®Öеĸõº¬Á¿×îÓÐÀû£¬Çë˵Ã÷ÀíÓÉ£º____________________________________________¡£

[×¢£ºÈ¥³ýÂÊ(£¥)=[(c0-c)£¯co]¡Á100£¥£¬Ê½ÖУºco¡ªÀíÇ°·ÏË®ÖÐCr2O72-µÄŨ¶È£¬c¡ª´¦Àíºó·ÏË®ÖÐCr2O72-µÄŨ¶È]

(3)³Áµíת»¯ÔÚÉú²úÖÐÒ²ÓÐÖØÒªÓ¦Óá£ÀýÈ磬ÓÃNa2CO3ÈÜÒº¿ÉÒÔ½«¹ø¯ˮ¹¸ÖеÄCaSO4ת»¯Îª½ÏÊèËɶøÒ×Çå³ýµÄCaCO3£¬¸Ã³Áµíת»¯´ïµ½Æ½ºâʱ£¬Æäƽºâ³£ÊýK£½_________(дÊýÖµ)¡£[ÒÑÖªKsp (CaSO4)=9.1x10-6£¬Ksp (CaCO3)=2.8¡Á10-9]

²é¿´´ð°¸ºÍ½âÎö>>

ͬ²½Á·Ï°²á´ð°¸